Diversity in the reaction modes of anionic and cationic stannyl reagents: γ-chloro allylstannanes as a vinyl carbene equivalent, and its application for (+/-)-bakuchiol synthesis

Article abstract of DOI:10.1016/0022-328X(94)80106-1

Diversity in the reaction modes of anionic stannyl reagents is demonstrated by synthon representation.A new cationic stannyl reagent, γ-chloro allylstannane, has been developed as a vinyl carbene equivalent, and its utility is demonstrated by (+)-bakuchio