Journal of the Chemical Society, Dalton Transactions p. 773 - 780 (1994)
Update date:2022-08-05
Topics:
Hart, Robert D.
Healy, Peter C.
Hope, Gregory A.
Turner, Duncan W.
White, Allan H.
Bis(triphenylphosphine)copper(I) fluoroacetate complexes have been prepared by the electrochemical oxidation of copper metal in acetonitrile solutions of triphenylphosphine and mono-, di- and tri-fluoroacetic acid respectively.Recrystallization from toluene yields unsolvated mononuclear complexes a with cell dimensions a ca. 18.0, b ca. 11.0 and c ca. 19.3 Angstroem and β ca. 120 deg.Residuals for the complexes with n = 1, 2 and 3 were R = 0.077, 0.045 and 0.048 for 3677, 2789 and 3527 'observed' 3?(I)> reflections respectively.The bond distances Cu-P are 2.232(3), 2.222(3); 2.234(2), 2.219(2); and 2.235(2) 2.228(2) Angstroem with the corresponding P-Cu-P angles increasing from 135.0(1) to 135.8(1) to 136.7(1) deg, this latter value being the largest recorded for a ca. 22.2, b ca. 18.5, c ca. 9.0 Angstroem) with monodentate carboxylate and co-ordinated ethanol; the monofluoroacetate is unsolvated.For
Contact:+86-18653358619
Address:zibo
Shanghai agrotree chemical co.,ltd.
Contact:+86-21-50117563
Address:Room 8A,liangfeng building,No.8 dongfang RD.pudong,shanghai,China
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd
Contact:+86-771-2311266
Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Ji'nan Orgachem Pharmaceutical Co.,Ltd
Contact:+86-531-82687810
Address:Jinan
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.
Contact:86-716-8331612
Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
Doi:10.1016/0040-4020(95)00201-I
(1995)Doi:10.1002/adsc.201400978
(2015)Doi:10.1016/j.tetasy.2013.12.005
(2014)Doi:10.1016/0022-328X(94)80025-1
(1994)Doi:10.1021/om00017a051
(1994)Doi:10.1016/j.ejmech.2013.11.002
(2014)
