
Journal of the American Chemical Society p. 4182 - 4192 (1980)
Update date:2022-08-02
Topics:
Collman, James P.
Brauman, John I.
Doxsee, Kenneth M.
Halbert, Thomas R.
Bunnenberg, Edward
et al.
The synthesis of "picket fence" porphyrin derivatives bearing covalently attached axial bases is described.The porphyrins have been well characterized, primarily as the iron(II) complexes, meso-tri(α,α,α-o-pivalamidophenyl)-β-o-5-(N-imidazolyl)valeramidophenylporphinatoiron(II) and meso-tri(α,α,α-o-pivalamidophenyl)-β-o-4-(N-imidazolyl)butyramidophenylporphyrinatoiron(II), by UV/visible, MCD, 1H NMR, and Moessbauer spectroscopy, magnetic susceptibility, and elemental analysis.Preliminary results of carbon monoxide binding studies are reported.
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