Journal of Heterocyclic Chemistry p. 1635 - 1640 (1993)
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Reaction of 1,2-epoxy-5α-3-ketosteroids with sodium azide produces a mixture of expected 2-azido-5α-Δ1-3-ketosteroids and novel [1,2- d]triazolosteroids. A possible pathway for formation of the latter involving 1,3-dipolar cycloaddition of sodi
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