Stereocontrolled synthesis of pyrimidine 2',3'-dideoxy-β-nucleosides by intramolecular glycosylation

DOI: 10.1016/S0040-4039(00)73186-8

Source and publish data:

Tetrahedron Letters p. 1883 - 1886 (1994)

Update date:2022-08-02

Topics:

Authors:

Sujino Sujino

Sugimura

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Article abstract of DOI:10.1016/S0040-4039(00)73186-8

β-2',3'-Dideoxynucleosides and their 3'-azido and 3'-fluoro substituted derivatives were synthesized in a stereocontrolled manner by the dimethyl(methylthio)sulfonium tetrafluoroborate promoted intramolecular glycosylation of phenyl 2,3-dideoxy-5-O-(2-pyrimidyl)-1-thioglycosides followed by hydrolysis or ammonolysis.

Full text of DOI:10.1016/S0040-4039(00)73186-8

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