Vicarious nucleophilic aromatic substitution via trapping of an α-ketosulfonium ion generated by Pummerer-type rearrangement of 2-(phenylsulfinyl)phenols: Preparation of biaryls

DOI: 10.1021/jo00091a003

Source and publish data:

Journal of Organic Chemistry p. 3248 - 3249 (1994)

Update date:2022-08-04

Topics:

Authors:

Jung Jung

Kim Kim

Von Dem Bussche

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00091a003

A new method for the nucleophilic substitution of phenols at the ortho position has been developed which uses as the key step the trapping of an α-ketosulfonium salt generated by a Pummerer rearrangement of 2-(phenylsulfinyl)phenols. In addition to prepar

Full text of DOI:10.1021/jo00091a003

Products guided by the article

Product name:5,5'-Dimethyl-3-phenylsulfanyl-biphenyl-2,2'-diol

Cas No:155675-34-6

R&D Labs maybe for 155675-34-6

Shanghai KFSL Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-39971718

Address:859 jiadingchengliu shanghai
ZUNYI CITY BEI YUAN CHEMICAL CO., LTD

website:http://www.china-beiyuan.com

Contact:+86-851-27751258

Address:Wujiang Building, Xianggang Road, Zunyi City, Guizhou Province, China
H&Y International Group Ltd

Contact:+86-571-86491666

Address:SHI XIANG ROAD
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Huangshan Violet Biological Technology Co., Ltd

Contact:+86-559-2335676

Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China

Relevant to this article

Efficient racemization of 1-phenylethylamine and its derivatives

Doi:10.1134/S1070363213120359
(2013)
Doi:10.1016/0008-6215(94)80057-X
(1994)
A new efficient bis(phosphinite)-ruthenium(II) catalyst system for the asymmetric transfer hydrogenation of aromatic ketones

Doi:10.1016/j.ica.2013.11.029
(2014)
Optimization, pharmacophore modeling and 3D-QSAR studies of sipholanes as breast cancer migration and proliferation inhibitors

Doi:10.1016/j.ejmech.2013.11.039
(2014)
Monomeric three-coordinate N-heterocyclic carbene nickel(I) complexes: Synthesis, structures, and catalytic applications in cross-coupling reactions

Doi:10.1021/acs.organomet.6b00419
(2016)
Labeled oxazaphosphorines for applications in mass spectrometry studies. 2. Synthesis of deuterium-labeled 2-dechloroethylcyclophosphamides and 2- and 3-dechloroethylifosfamides

Doi:10.1002/jlcr.3142
(2014)

Article Doi