Vicarious nucleophilic aromatic substitution via trapping of an α-ketosulfonium ion generated by Pummerer-type rearrangement of 2-(phenylsulfinyl)phenols: Preparation of biaryls

DOI: 10.1021/jo00091a003

Source and publish data:

Journal of Organic Chemistry p. 3248 - 3249 (1994)

Update date:2022-08-04

Topics:

Authors:

Jung Jung

Kim Kim

Von Dem Bussche

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Article abstract of DOI:10.1021/jo00091a003

A new method for the nucleophilic substitution of phenols at the ortho position has been developed which uses as the key step the trapping of an α-ketosulfonium salt generated by a Pummerer rearrangement of 2-(phenylsulfinyl)phenols. In addition to prepar

Full text of DOI:10.1021/jo00091a003

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