Vicarious nucleophilic aromatic substitution via trapping of an α-ketosulfonium ion generated by Pummerer-type rearrangement of 2-(phenylsulfinyl)phenols: Preparation of biaryls

DOI: 10.1021/jo00091a003

Source and publish data:

Journal of Organic Chemistry p. 3248 - 3249 (1994)

Update date:2022-08-04

Topics:

Authors:

Jung Jung

Kim Kim

Von Dem Bussche

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00091a003

A new method for the nucleophilic substitution of phenols at the ortho position has been developed which uses as the key step the trapping of an α-ketosulfonium salt generated by a Pummerer rearrangement of 2-(phenylsulfinyl)phenols. In addition to prepar

Full text of DOI:10.1021/jo00091a003

Products guided by the article

Product name:5,5'-Dimethyl-3-phenylsulfanyl-biphenyl-2,2'-diol

Cas No:155675-34-6

R&D Labs maybe for 155675-34-6

WEIFANG RICHEM INTERNATIONAL LTD

Contact:86-536-2222176

Address:weifang,shandong
Zhejiang Chemicals Import & Export Corporation

Contact:86-571-87043088

Address:No.37,Qingchun Road,Hangzhou,China
HANGZHOU TOYOND BIOTECH CO., LTD

Contact:+86-571-86965177

Address:No. 189, Fengqi East Road, Hangzhou, China
Shanghai chemrole co.,ltd

Contact:021-50278900

Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
Sinoway Industrial Co., Ltd.

website:http://www.china-sinoway.com

Contact:+86-592-5853819

Address:16/F,Huicheng Comm,Complex,No839 XiaHe Rd, Xiamen,China

Relevant to this article

Efficient racemization of 1-phenylethylamine and its derivatives

Doi:10.1134/S1070363213120359
(2013)
Doi:10.1016/0008-6215(94)80057-X
(1994)
A new efficient bis(phosphinite)-ruthenium(II) catalyst system for the asymmetric transfer hydrogenation of aromatic ketones

Doi:10.1016/j.ica.2013.11.029
(2014)
Optimization, pharmacophore modeling and 3D-QSAR studies of sipholanes as breast cancer migration and proliferation inhibitors

Doi:10.1016/j.ejmech.2013.11.039
(2014)
Monomeric three-coordinate N-heterocyclic carbene nickel(I) complexes: Synthesis, structures, and catalytic applications in cross-coupling reactions

Doi:10.1021/acs.organomet.6b00419
(2016)
Labeled oxazaphosphorines for applications in mass spectrometry studies. 2. Synthesis of deuterium-labeled 2-dechloroethylcyclophosphamides and 2- and 3-dechloroethylifosfamides

Doi:10.1002/jlcr.3142
(2014)

Article Doi