Total synthesis of Taxol. 3. Formation of Taxol's ABC ring skeleton

DOI: 10.1021/ja00107a008

Source and publish data:

Journal of the American Chemical Society p. 645 - 652 (1995)

Update date:2022-08-02

Topics:

Authors:

Nicolaou

Yang Yang

Liu Liu

Nantermet

Claiborne

Renaud Renaud

Guy Guy

Shibayama

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Article abstract of DOI:10.1021/ja00107a008

The synthesis of Taxol's ABC ring system has been achieved. The Shapiro coupling of an aldehydic C ring synthon (8) with an anionic A ring synthon derived from hydrazone 9 gave, diastereoselectively, A-B conjugate 10. Functional group manipulations and Mc

Full text of DOI:10.1021/ja00107a008

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