Lewis Acid-Promoted Selective Rearrangement of Trisubstituted Epoxides to Aldehydes or Ketones

DOI: 10.1016/S0040-4020(01)90389-8

Source and publish data:

Tetrahedron p. 3663 - 3672 (1994)

Update date:2022-08-04

Topics:

Authors:

Maruoka, Keiji

Murase, Noriaki

Bureau, Ronan

Ooi, Takashi

Yamamoto, Hisashi

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Article abstract of DOI:10.1016/S0040-4020(01)90389-8

Rearrangement of trisubstituted epoxides has been effected under the influence of various Lewis acids.Among these, methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) can be selectively rearranged from trisubstituted epoxides to aldehydes, while

Full text of DOI:10.1016/S0040-4020(01)90389-8

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