Lithiation of 2-chloromethylpyridine: Synthesis of 2-oxiranyl pyridines

DOI: 10.1016/S0040-4039(00)76860-2

Source and publish data:

Tetrahedron Letters p. 3175 - 3178 (1994)

Update date:2022-08-02

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Authors:

Florio Florio

Troisi Troisi

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Article abstract of DOI:10.1016/S0040-4039(00)76860-2

Deprotonation of 2-chloromethylpyridine 1a with lithium diisopropylamide (LDA) in tetrahydrofuran (THF) at -78°C gives a red solution of 2-pyridiylchloromethyllithium 1b, which reacts with carbonyl compounds furnishing oxiranes 2.

Full text of DOI:10.1016/S0040-4039(00)76860-2

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