The formation of 3-methyl-1a,7b-dihydro-1H-cycloprop[c]isoquinoline from trans-N-[2-(2-acetylphenyl)cyclopropyl]-2-(trimethylsilyl)ethylcarbama te

DOI: 10.1016/S0040-4039(00)76924-3

Source and publish data:

Tetrahedron Letters p. 3417 - 3420 (1994)

Update date:2022-08-03

Topics:

Authors:

Appelberg

Vallgarda

Hacksell

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)76924-3

3-methyl-1a,7b-dihydro-1H-cycloprop[c]isoquinoline is formed from trans-2-(2-acetylphenyl)cyclopropylamine generated in situ. The mechanism for this reaction appears to involve the formation of a cis-arylcyclopropylamine via a homoconjugated intermediate.

Full text of DOI:10.1016/S0040-4039(00)76924-3

Products guided by the article

Product name:(1R,2R)-2-(2-acetylphenyl)cyclopropane carboxylic acid

Cas No:156338-65-7

R&D Labs maybe for 156338-65-7

YingYing Pharmaceutical Co.,Ltd

Contact:86-18854126208

Address:55#, yingxiongshan road
Jiangxi Hessence Chemicals Co., Ltd.

Contact:+86 796 3511924

Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)

Contact:+86-21-54159691

Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
QUZHOU ZIO I/E CO.;LTD

Contact:13357117572

Address:No.149 Shiji dadao Road.

Relevant to this article

A novel entry toward 2-imino-1,3-thiazolidines and 2-imino-1,3-thiazolines by ring transformation of 2-(thiocyanomethyl)aziridines

Doi:10.1021/jo048486f
(2005)
Transition-Metal-Free Catalytic Hydrodefluorination of Polyfluoroarenes by Concerted Nucleophilic Aromatic Substitution with a Hydrosilicate

Doi:10.1002/anie.201708003
(2017)
Regioselectivity in the 1,3-Dipolar Cycloaddition of Nitrile Oxides to N-(3,5-Dichlorophenyl)itaconimide

Doi:10.1007/BF00811316
(1994)
Synthesis and biological activities of the optical isomers of (±)-4-amino-5-chloro-2-ethoxy-N-[[4-(4-fluorobenzyl)-2-morpholinyl]me thyl]benzamide (Mosapride)

Doi:10.1248/cpb.42.877
(1994)
Halogeno(phenyl)-, Diphenyl-, Amino(phenyl)carben- und Phenylimido-Osmiumkomplexe durch Reaktion von <(Mes)Os(CNR)Cl2> mit Phenyllithium und Phenyl-Grignardreagenzien

Doi:10.1016/0022-328X(94)88074-3
(1994)
3-Di-[(S)-2-acetoxypropanoyl] aminoquinazolin-4(3H)-ones: Stereostructure and application in kinetic resolution of amines

Doi:10.1016/S0040-4039(00)00139-8
(2000)

Article Doi