The formation of 3-methyl-1a,7b-dihydro-1H-cycloprop[c]isoquinoline from trans-N-[2-(2-acetylphenyl)cyclopropyl]-2-(trimethylsilyl)ethylcarbama te

DOI: 10.1016/S0040-4039(00)76924-3

Source and publish data:

Tetrahedron Letters p. 3417 - 3420 (1994)

Update date:2022-08-03

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Authors:

Appelberg

Vallgarda

Hacksell

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Article abstract of DOI:10.1016/S0040-4039(00)76924-3

3-methyl-1a,7b-dihydro-1H-cycloprop[c]isoquinoline is formed from trans-2-(2-acetylphenyl)cyclopropylamine generated in situ. The mechanism for this reaction appears to involve the formation of a cis-arylcyclopropylamine via a homoconjugated intermediate.

Full text of DOI:10.1016/S0040-4039(00)76924-3

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