
Journal of Organometallic Chemistry p. 205 - 212 (1994)
Update date:2022-08-03
Topics:
Werner, Helmut
Wecker, Ulrich
Peters, Karl
Schnering, Hans Georg von
On treatment of <(Mes)Os(CNR)Cl2> (2: R=t-Bu; 4: R=Cy; 5: R=Xyl)* with C6H5MgBr, the diphenyl- and the bromo(phenyl)osmium(II) compounds <(Mes)OsPh2(CNR)> (7-9) and <(Mes)OsPh(CNR)Br> (10-12) are formed.As a minor product in the reaction of 4 with C6H5MgBr, the aminocarbene complex <(Mes)OsPh2<(=C(NHCy)Ph>> (6) is obtained.From <(Mes)Os(CNPh)Cl2> (3) and C6H5MgBr, besides <(Mes)OsPh(CNR)Br> (14) the five-membered ring compound
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