Journal of molecular catalysis p. 257 - 266 (1994)
Update date:2022-07-30
Topics:
do Nascimento Filho
de Lima
dos Santos Lima Neto
Franco
By a kinetic approach, the trans-effects and trans-influences of nineteen tertiary phosphane ligands were evaluated for a hexacoordinated d6-low spin metal center. Plots of specific rate constants versus formal potentials for Ru(III)/Ru(II) couples provide a simple, reliable and efficient method to predict phosphane reactivity and are useful as a guide for design of new catalysts.
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