Chemical and Pharmaceutical Bulletin p. 2003 - 2008 (1996)
Update date:2022-08-03
Topics: Aldol Reaction
Iseki, Katsuhiko
Oishi, Satoshi
Kobayashi, Yoshiro
In the Oppolzer aldol reaction, aldehyde reacts exclusively on the Si face (C(α)-Si attack) of the double bond of the boryl enolate 2 derived from (1S,2R)-N-propionylbornane-10,2-sultam (1), providing only 3a stereoselectively. Hexafluoroacetone (4) cause
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