Tetrahedron Letters p. 6919 - 6922 (1995)
Update date:2022-07-31
Topics: Cationic nucleophilic Monosubstituted Transition state Charge delocalization
Liu, Kwang-Ting
Chin, Chien-Pu
Lin, Yen-Shyi
Tsao, Meng-Lin
Solvolyses of monosubstituted benzhydryl bromides gave excellent linear correlations of logk with ?(1+) constants, and not with Y(BnBr) or Y(Br).Correlation analyses against corresponding logk of α-tert-butyl-(2-naphthyl)methyl bromide provided evidence for the importance of different extent of solvation in delocalized transition state and for nucleophilic solvent intervention in the solvolysis of benzhydryl systems.
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()Doi:10.1063/1.478869
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