Tetrahedron p. 5829 - 5844 (1994)
Update date:2022-07-31
Topics:
Najera, Carmen
Sansano, Jose Miguel
The alkylation of the monolithium derivative 5 of 2-(chloromethyl)-3-tosylpropene (1) with bromo- or iodo-methyltrimethylsilane affords the β-silyl sulfone 7, which after nucleophilic substitution of the chlorine atom followed by β-elimination of tosyltrimethylsilane, promoted by tetrabutylammonium fluoride (TBAF), gives 2-substituted conjugated dienes 6 and the outer-ring diene 14.Racemic ipsenol (10b), an aggregation pheromone of the bark beetle Ips paraconfusus Lanier, is prepared.
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Doi:10.1002/bkcs.10259
(2015)Doi:10.1016/0040-4039(90)87036-Y
(1990)Doi:10.1016/j.polymer.2014.01.028
(2014)Doi:10.1021/om00020a052
(1994)Doi:10.1021/ja411433f
(2014)Doi:10.1016/S0040-4020(01)80636-0
(1994)
