Tetrahedron p. 5413 - 5424 (1994)
Update date:2022-08-03
Topics:
Barillier, Daniel
Levillain, Jocelyne
Vazeux, Michel
New syntheses of α-thiosubstituted carbonyl compounds with the carbonyl carbon being the one that originally does not carry the sulfoxide group from six-membered ring α,β-epoxysulfoxides and several halides-based electrophiles are described. Mechanistic considerations for deoxygenation as well as dehydration reactions are also discussed. In addition, methodology for achieving 1,2-carbonyl transposition starting with isomerically pure cyclohexenyl sulfides derived from isophorone and cholestan-3-one is briefly reported.
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Doi:10.1016/0040-4020(96)00498-X
(1996)Doi:10.1021/acs.joc.6b02344
(2017)Doi:10.1016/j.jorganchem.2019.121039
(2020)Doi:10.1039/c9dt00468h
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(2014)Doi:10.1139/v94-170
(1994)
