A β,β,β-Trialkoxyethyllithium Stable towards Fragmentation: a Carboxyl Protected Acetic Acid Dianion Equivalent

DOI: 10.1016/S0040-4020(01)85292-3

Source and publish data:

Tetrahedron p. 8099 - 8102 (1994)

Update date:2022-08-04

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Authors:

Chandrasekhar, Sosale

Roy, Chandra Deo

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Article abstract of DOI:10.1016/S0040-4020(01)85292-3

The novel alkyllithium 1b is not only intriguinly stable towards fragmentation, but also a synthetically useful reagent, complementing current carboxylic ester enolate methodology.Its design is based on interesting mechanistic principles, and harnesses the known stability of the 2,4,10-trioxaadamantane framework.

Full text of DOI:10.1016/S0040-4020(01)85292-3

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