Tetrahedron Letters p. 1223 - 1226 (1994)
Update date:2022-07-29
Topics:
Oikawa, Hideaki
Matsuda, Isamu
Ichihara, Akitami
Kohmoto, Keisuke
Degradation of AAL-toxin 1 a host-specific phytotoxin and synthesis of model aminotriol 7a-7d allowed us to determine the absolute configuration of C(1)-C(5) fragment as 2S, 4S and 5R. Unusually rigid conformation of this acyclic fragment was also discussed.
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