An Efficient and Flexible Route to (+)-Polyoxamic Acid using Diastereoselective Epoxidation of 1-Arylthio-1-nitroalkenes

DOI: 10.1039/c39940000095

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 95 - 96 (1994)

Update date:2022-08-02

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Authors:

Jackson, Richard F. W.

Palmer, Nicholas J.

Wythes, Martin J.

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Article abstract of DOI:10.1039/c39940000095

Polyoxamic acid 4a is prepared by a short and efficient process in which the key steps are the highly diastereoselective nucleophilic epoxidation of the D-threitol-derived alkene 6 using potassium tert-butylperoxide, followed by reaction of the oxirane 7a with ammonia.

Full text of DOI:10.1039/c39940000095

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