Journal of the Chemical Society, Dalton Transactions p. 1949 - 1962 (1994)
Update date:2022-08-02
Topics:
Belchem, Gary
Steed, Jonathan W.
Tocher, Derek A.
Reaction of the ruthenium(IV) chloro-bridged dimer <a range of alkane- and arene-thiols in CH2Cl2 resulted in the formation of the simple, bridge-cleaved adducts a single geometrical isomer.In the case of 7 and 12 separation of the two diastereomeric forms proved possible because of their remarkably different solubilities in methanol, and their kinetic inertness.Reactions of 2 and 3 with 1 gave the mixed-bridge chloro/thiolato complexes <a range of Ru(II) and Rh(III)-containing compounds enabled the isolation of a number of unusual mixed-valence and mixed-metal complexes containing one or two bridging ethanethiolate ligands.The ruthenium(IV)-rhodium(III) compounds <(η3:η3-C10H16)ClRu(μ-Cl)(μ-SEt)RhCl(η5-C5Me5)> and <(η3:η3-C10H16)ClRu(μ-SEt)2RhCl2(PMe2Ph)2> have been characterized by X-ray crystallography.
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