Synthesis of the Tricyclo3,8>pentadecane (ABC) Ring System of Taxane Diterpenes

DOI: 10.1016/S0040-4039(00)76878-X

Source and publish data:

Tetrahedron Letters p. 3255 - 3258 (1994)

Update date:2022-08-05

Topics:

Authors:

Romero, Miguel A.

Franco, Ruben Perez

Cruz-Almanza, Raymundo

Padilla, Fernando

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Article abstract of DOI:10.1016/S0040-4039(00)76878-X

The synthesis of diketone 14 possessing the tricyclo<9.3.1.0^3,8>pentadecane (ABC) taxane ring system is described.This concise approach employs a Wacker oxidation, intramolecular aldol condensation-dehydration, and a highly exo-stereoselective

Full text of DOI:10.1016/S0040-4039(00)76878-X

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