Reactions of electron-rich arylpalladium complexes with olefins. Origin of the chelate effect in vinylation catalysis

DOI: 10.1021/om00021a021

Source and publish data:

Organometallics p. 3465 - 3479 (1994)

Update date:2022-08-04

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Authors:

Portnoy Portnoy

Ben-David

Rousso Rousso

Milstein

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Article abstract of DOI:10.1021/om00021a021

Reaction of (dippp)Pd(Ph)Cl (1) with norbornene or styrene yields (dippp)PdCl₂ (8) and (dippp)Pd(η²-olefin). Kinetic follow-up reveals fast formation of (dippp)Pd(phenylnorbornyl)-Cl (10), followed by its slow decomposition, with k View More

Full text of DOI:10.1021/om00021a021

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