Biotransformations of racemic 2,3-allenenitriles in biphasic systems: Synthesis and transformations of enantioenriched axially chiral 2,3-allenoic acids and their derivatives

DOI: 10.1021/jo500228z

Source and publish data:

Journal of Organic Chemistry p. 3103 - 3110 (2014)

Update date:2022-09-26

Topics:

Authors:

Ao, Yu-Fei

Wang, De-Xian

Zhao, Liang

Wang, Mei-Xiang

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Article abstract of DOI:10.1021/jo500228z

Catalyzed by Rhodococcus erythropolis AJ270 whole cells in an aqueous phosphate buffer-n-hexane biphasic system, racemic axially chiral 2,3-allenenitriles underwent hydrolysis to afford enantioenriched (aR)-2,3-allenamides and (aS)-2,3-allenoic acids with

Full text of DOI:10.1021/jo500228z

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