Asymmetric synthesis of allylsilanes by palladium-catalyzed asymmetric reduction of allylic carbonates with formic acid

DOI: 10.1016/S0040-4039(00)76975-9

Source and publish data:

Tetrahedron Letters p. 4813 - 4816 (1994)

Update date:2022-08-05

Topics:

Authors:

Hayashi, Tamio

Iwamura, Hiroshi

Uozumi, Yasuhiro

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Article abstract of DOI:10.1016/S0040-4039(00)76975-9

Reduction of 3-alkyl-3-trialkylsilyl-2-propenyl methyl carbonates with formic acid and 1,8-bis(dimethylamino)naphthalene in the presence of a palladium catalyst (3 mol %) coordinated with (R)-3-diphenylphosphino-3'-methoxy-4,4'-biphenanthryl (MOP-phen) ga

Full text of DOI:10.1016/S0040-4039(00)76975-9

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Product name:(R)-3-phenyl-3-triethylsilyl-1-propene

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