Tetrahedron Letters p. 3931 - 3934 (1994)
Update date:2022-07-30
Topics:
Baussanne, Isabelle
Chiaroni, Angele
Husson, Henri-Philippe
Riche, Claude
Royer, Jacques
A new chiral non-racemic γ-lactam 1 easily prepared in one step from (R)-(-)-phenylglycinol was bis-alkylated α to the carbonyl function in very high to complete diastereoselectivity. The stereochemistry at the so-formed chiral quaternary center was ascertained through an X-ray crystallographic study.
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