
Chemistry Letters p. 1459 - 1462 (1994)
Update date:2022-07-31
Topics:
Kira, Mitsuo
Tokura, Satoshi
A novel type of photoisomerization of aryldisilanes, which involves 1,3-migration of a β-trimethylsilyl group from silicon to a fluorinated aromatic carbon accompanied by backward 1,3-migration of the fluorine to the α-silicon, was found during irradiation of 2,6-difluorophenyldisilanes.
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