A General Method of Promoting Agostic Interactions (Ru-Ha-C) using Azine Phosphines

DOI: 10.1039/c39940001201

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1201 - 1202 (1994)

Update date:2022-08-02

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Authors:

Perera, Sarath D.

Shaw, Bernard L.

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Article abstract of DOI:10.1039/c39940001201

Treatment of with azine phosphines gives complexes showing strong agostic interactions between ruthenium and C-H bonds of tert-butyl, methyl, aryl or alkenyl groups in dynamic systems; for example, all nine hydrogens of a tert-butyl group are agostically interacting with ruthenium on the NMR timescale at 20 deg C.

Full text of DOI:10.1039/c39940001201

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Product name:{RuCl₂(P(C₆H₅)3)(P(C₆H₅)2)CH₂C(C(CH₃)3)NN(CH(C₆H₄)N(CH₃)2)}

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