A General Method of Promoting Agostic Interactions (Ru-Ha-C) using Azine Phosphines

DOI: 10.1039/c39940001201

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1201 - 1202 (1994)

Update date:2022-08-02

Topics:

Authors:

Perera, Sarath D.

Shaw, Bernard L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940001201

Treatment of with azine phosphines gives complexes showing strong agostic interactions between ruthenium and C-H bonds of tert-butyl, methyl, aryl or alkenyl groups in dynamic systems; for example, all nine hydrogens of a tert-butyl group are agostically interacting with ruthenium on the NMR timescale at 20 deg C.

Full text of DOI:10.1039/c39940001201

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{RuCl₂(P(C₆H₅)3)(P(C₆H₅)2)CH₂C(C(CH₃)3)NN(CH(C₆H₄)N(CH₃)2)}

Cas No:158308-33-9

R&D Labs maybe for 158308-33-9

Cerametek Materials（ShenZhen）Co., Ltd.

Contact:+86-755-2324.2554

Address:A3-#9, YongChuan Street, Suite 501
Zhaodu Fine Chemical Plant

Contact:86-310-8067016

Address:East Fuhua Road,Tiexi Chemical Industrial Estate,Hebei,China
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Anhui Gusheng Import&Export CO.,LTD

Contact:86-551-63662296

Address:Jinzhai Road NO.162 ,hefei, china
wuxi huabin bio-tech Co.,Ltd(expird)

Contact:86-0510-85133006

Address:hubin road NO157

Relevant to this article

Synthesis of bisubstrate analogues targeting α-1,3-fucosyltransferase and their activities

Doi:10.1039/b513897c
(2006)
A convenient synthetic route for the preparation of nonsymmetric metallosalphen complexes

Doi:10.1002/ejic.200500628
(2005)
A general and efficient route to thionoesters via thionoacyl nitrobenzotriazoles

Doi:10.1021/jo981985u
(1999)
Doi:10.1021/ja01297a028
(1936)
5-<(Aminoalkyl)amino>-Substituted Anthra<1,9-cd>pyrazol-6(2H)-ones as Novel Anticancer Agents. Synthesis and Biological Evaluation

Doi:10.1021/jm00369a002
(1984)
Spectroscopic and Kinetic Characterization of Diphenyldiazomethane Radical Anion

Doi:10.1021/j100381a041
(1990)

Article Doi