Asymmetric metal carbene insertion into the Si-H bond

DOI: 10.1016/S0040-4039(00)60729-3

Source and publish data:

Tetrahedron Letters p. 4565 - 4568 (1994)

Update date:2022-08-03

Topics:

Authors:

Landais, Yannick

Planchenault, Denis

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Article abstract of DOI:10.1016/S0040-4039(00)60729-3

α-silyl-α-substituted acetic esters have been prepared in good yields and reasonable diastereoselectivities using an asymmetric metal carbene insertion into the Si-H bond. Optically active 1,2-diols were then prepared after reduction of the ester and conv

Full text of DOI:10.1016/S0040-4039(00)60729-3

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