(4S,8S)-4,8-Bis(diphenylmethyl)-1,5,7-triazabicyclodec-5-ene; a Hindered, Chiral, Bicyclic Guanidine Base with Effective C2-Symmetry

DOI: 10.1039/c39940001875

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1875 - 1876 (1994)

Update date:2022-08-03

Topics:

Authors:

Boyle, Peter H.

Davis, Anthony P.

Dempsey, Kevin J.

Hosken, Gladys D.

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Article abstract of DOI:10.1039/c39940001875

The title compound 5 is prepared from L-methionine and investigated by computational, NMR spectroscopic and other techniques; the results indicate that the N/NH groups of 5 and its conjugate acid occupy hindered, chiral environments due to the disposition of the bulky diphenylmethyl substituents.

Full text of DOI:10.1039/c39940001875

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