Synthesis of an optically active hydroxy diphosphine, a new ligand for asymmetric catalysis

DOI: 10.1016/0040-4039(94)88078-6

Source and publish data:

Tetrahedron Letters p. 6071 - 6074 (1994)

Update date:2022-09-26

Topics:

Authors:

Boerner, Armin

Holz, Jens

Kless, Achim

Heller, Detlef

Berens, Ulrich

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Article abstract of DOI:10.1016/0040-4039(94)88078-6

The synthesis of (4R, 5R)-4,5-bis(diphenylphosphinomethyl)-2-hydroxymethyl-2-phenyl-1,3-diox olane 1 which is related to DIOP is described. The application of this new ligand in asymmetric catalysis is illustrated in the stereodifferentiating hydrogenation.

Full text of DOI:10.1016/0040-4039(94)88078-6

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