Opening the Way to Catalytic Aminopalladation/Proxicyclic Dehydropalladation: Access to Methylidene γ-Lactams

DOI: 10.1021/acs.orglett.6b00143

Source and publish data:

Organic Letters p. 1020 - 1023 (2016)

Update date:2022-09-26

Topics:

Authors:

Lorion, Mélanie M.

Duarte, Filipe J. S.

Calhorda, Maria José

Oble, Julie

Poli, Giovanni

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/acs.orglett.6b00143

A new aerobic intramolecular palladium(II)-based catalytic system that triggers aminopalladation/dehydropalladation of N-sulfonylalkenylamides to give the corresponding methylidene γ-lactams has been identified. Use of triphenylphosphine and chloride anio

Full text of DOI:10.1021/acs.orglett.6b00143

Products guided by the article

Product name:6-methylidene-1-tosylpiperidin-2-one

Cas No:1590412-15-9

R&D Labs maybe for 1590412-15-9

Nanjing Zelang Medical Technology Co. Ltd

Contact:86-25-83063290/13770714480

Address:Ganjiabian 108# 01 Unit,701-702 room,Yao Hua Street,Qixia District,Nanjing,Jiangsu,China
SJZ THLD IMP & EXP CO LTD

website:http://www.truewingroup.com

Contact:86-311-66699812

Address:NO.600 ZHONGSHAN EAST ROAD SHIJIAZHUANG
Liao Cheng All Win Chemicals Co.,LTD

Contact:86+0635-2991582

Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
Shandong Xinke Petrochemical Co., Ltd.

Contact:+86-546-7277016

Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China

Relevant to this article

Synthesis and anticonvulsant activity evaluation of 7-alkoxy-2, 4-dihydro-1H-benzo[b][1,2,4]triazolo[4,3-d][1,4]thiazin-1-ones in various murine experimental seizure models

Doi:10.1007/s00044-013-0778-y
(2014)
Copper(II) and gallium(III) complexes of trans -Bis(2-hydroxybenzyl) cyclen derivatives: Absence of a cross-bridge proves surprisingly more favorable

Doi:10.1021/ic403156h
(2014)
Boranes in synthesis - VII. Synthesis of 2-dialkylamino-6,6- dimethylbicyclo[3.1.1]heptan-3-ols from (R)-(+)-nopinone. Chiral auxiliaries for the addition of diethylzinc to aromatic aldehydes

Doi:10.1016/S0957-4166(97)00566-1
(1997)
Photoactive amorphous molecular materials based on quinoline amines and their synthesis by Friedl?nder condensation reaction

Doi:10.1016/j.tet.2010.09.108
(2010)
Microwave assisted one-pot tandem three-component synthesis of 2,4,5-triary1-2-4-dihydro-3H-1,2,4-triazol-3-one derivatives

Doi:10.1016/j.cclet.2013.12.018
(2014)
Catalytic coupling of N-benzylic sulfonamides with silylated nucleophiles at room temperature

Doi:10.1039/c0cc00765j
(2010)

Article Doi