Pinacol closure of oxygenated taxane skeleta at C-1-C-2 with stereoinduction by oxygen substituents at C-9 and C-10

DOI: 10.1016/S0040-4039(00)73292-8

Source and publish data:

Tetrahedron Letters p. 4959 - 4962 (1994)

Update date:2022-08-05

Topics:

Authors:

Swindell, Charles S.

Fan, Weiming

Klimko, Peter G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)73292-8

The treatment of keto aldehydes 4 and 5 with low-valent Ti results in stereoselective intramolecular pinacol couplings that lead to optically active oxygenated taxane skeleta 2 and 3.

Full text of DOI:10.1016/S0040-4039(00)73292-8

Products guided by the article

Product name:(R)-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-(1-methoxy-1-methyl-ethoxy)-acetaldehyde

Cas No:159143-36-9

R&D Labs maybe for 159143-36-9

Liaoning Yufeng Chemical Co.,Ltd.

Contact:86-0419-3418888

Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
Chengda Pharmaceuticals Co., Ltd.

Contact:+86-573-84601188

Address:hengshan Road 5# in Jiashan, zhejiang
Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Weinan Rigel Pharm Co., Ltd.

Contact:+86-913-2223392

Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China
Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA

Relevant to this article

SYNTHESIS AND BIOLOGICAL ACTIVITY OF 2-SILA-5-MORPHOLINONES

Doi:10.1007/BF02285398
(1994)
Synthesis of carbazole-based hetero-core-modified porphyrins

Doi:10.1039/c3ob42564a
(2014)
A new zirconocene complex, [{η⁵-C₅H₄-C(CH₂) ₅(CH₂)₂CH(CH₃)₂} ₂ZrCl₂]

Doi:10.1107/S0108270195005543
(1996)
Synthesis of proposed aglycone of mandelalide A

Doi:10.1021/ol500875e
(2014)
Cross-dehydrogenative couplings between indoles and β-keto esters: Ligand-assisted ligand tautomerization and dehydrogenation via a proton-assisted electron transfer to Pd(II)

Doi:10.1021/ja501681y
(2014)
Harnessing the ortho-directing ability of the azetidine ring for the regioselective and exhaustive functionalization of arenes

Doi:10.1002/chem.201403141
(2014)

Article Doi