Pinacol closure of oxygenated taxane skeleta at C-1-C-2 with stereoinduction by oxygen substituents at C-9 and C-10

DOI: 10.1016/S0040-4039(00)73292-8

Source and publish data:

Tetrahedron Letters p. 4959 - 4962 (1994)

Update date:2022-08-05

Topics:

Authors:

Swindell, Charles S.

Fan, Weiming

Klimko, Peter G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)73292-8

The treatment of keto aldehydes 4 and 5 with low-valent Ti results in stereoselective intramolecular pinacol couplings that lead to optically active oxygenated taxane skeleta 2 and 3.

Full text of DOI:10.1016/S0040-4039(00)73292-8

Products guided by the article

Product name:(R)-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-(1-methoxy-1-methyl-ethoxy)-acetaldehyde

Cas No:159143-36-9

R&D Labs maybe for 159143-36-9

Qingdao Kingway Pharmtech Co., Ltd.

Contact:86-532-87118899

Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China
Wuxi Innopal International Trade CO.,LTD

Contact:+86-510-80711901-8003

Address:Room 402,Building 5,Longze Garden,No.17,South huanjiu Road,Yixing City, Jiangsu,China
Luoyang Aoda chemical Co.,Ltd.

Contact:+86-379-67518785 67516588

Address:MiaoWan industry district,YanShi City,Henan,China
Qingdao Kingway Pharmtech Co., Ltd.

Contact:86-532-87118899

Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China
Shangyu Sanhechemicals Co.,LTD.

Contact:86-0571-56696839

Address:Num.2952,Nanhuan Road,Binjiang District,Hangzhou,China

Relevant to this article

SYNTHESIS AND BIOLOGICAL ACTIVITY OF 2-SILA-5-MORPHOLINONES

Doi:10.1007/BF02285398
(1994)
Synthesis of carbazole-based hetero-core-modified porphyrins

Doi:10.1039/c3ob42564a
(2014)
A new zirconocene complex, [{η⁵-C₅H₄-C(CH₂) ₅(CH₂)₂CH(CH₃)₂} ₂ZrCl₂]

Doi:10.1107/S0108270195005543
(1996)
Synthesis of proposed aglycone of mandelalide A

Doi:10.1021/ol500875e
(2014)
Cross-dehydrogenative couplings between indoles and β-keto esters: Ligand-assisted ligand tautomerization and dehydrogenation via a proton-assisted electron transfer to Pd(II)

Doi:10.1021/ja501681y
(2014)
Harnessing the ortho-directing ability of the azetidine ring for the regioselective and exhaustive functionalization of arenes

Doi:10.1002/chem.201403141
(2014)

Article Doi