Pinacol closure of oxygenated taxane skeleta at C-1-C-2 with stereoinduction by oxygen substituents at C-9 and C-10

DOI: 10.1016/S0040-4039(00)73292-8

Source and publish data:

Tetrahedron Letters p. 4959 - 4962 (1994)

Update date:2022-08-05

Topics:

Authors:

Swindell, Charles S.

Fan, Weiming

Klimko, Peter G.

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Article abstract of DOI:10.1016/S0040-4039(00)73292-8

The treatment of keto aldehydes 4 and 5 with low-valent Ti results in stereoselective intramolecular pinacol couplings that lead to optically active oxygenated taxane skeleta 2 and 3.

Full text of DOI:10.1016/S0040-4039(00)73292-8

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