A facile synthesis of homochiral 1-norbornanecarboxylic acids and 1-norbornanecarbonitriles

DOI: 10.1016/0957-4166(94)80130-4

Source and publish data:

Tetrahedron Asymmetry p. 1599 - 1603 (1994)

Update date:2022-08-03

Topics:

Authors:

Garcia Martinez

Teso Vilar

Garcia Fraile

De La Moya Cerero

Gonzelez-Fleitas De Diego

Subramanian

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Article abstract of DOI:10.1016/0957-4166(94)80130-4

A general method for the preparation of the title compounds from naturally occurring homochiral 2-norbornanones is presented. The key step is the Tf₂O induced Wagner-Meerwein rearrangement of the corresponding cyanohydrins.

Full text of DOI:10.1016/0957-4166(94)80130-4

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Product name:(+)-(1R)-3,3-dimethyl-2-methylene-1-norbornanecarbonitrile

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