Substrate-controlled Crotylboration from N-(tert-Butoxycarbonyl)amino Aldehydes

DOI: 10.1039/P19940001275

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1275 - 1280 (1994)

Update date:2022-08-02

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Authors:

Niel, Gilles

Roux, Florence

Maisonnasse, Ysadora

Maugras, Isabelle

Poncet, Joel

Jouin, Patrick

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Article abstract of DOI:10.1039/P19940001275

Chiral or achiral (Z)-crotylorganoboron compounds add preferentially anti to N-(tert-butoxacrbonyl)amino aldehydes.N-(tert-Butoxycarbonyl)prolinal 3 presents a remarkably high diastereofacial selectivity.Double stereodifferentiation, starting from compoun

Full text of DOI:10.1039/P19940001275

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