Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set

DOI: 10.1002/anie.201806168

Source and publish data:

Angewandte Chemie - International Edition p. 10651 - 10655 (2018)

Update date:2022-08-04

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Authors:

Pollard, Victoria A.

Fuentes, M. ángeles

Kennedy, Alan R.

McLellan, Ross

Mulvey, Robert E.

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Article abstract of DOI:10.1002/anie.201806168

Bimetallic lithium aluminates and neutral aluminum counterparts are compared as catalysts in hydroboration reactions with aldehydes, ketones, imines and alkynes. Possessing Li–Al cooperativity, ate catalysts are found to be generally superior. Catalytic a

Full text of DOI:10.1002/anie.201806168

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