New Synthesis of α-Amino Acid N-Carboxy Anhydrides through Baeyer-Villiger Oxidation of α-Keto β-Lactams

DOI: 10.1021/jo00090a033

Source and publish data:

Journal of Organic Chemistry p. 3123 - 3130 (1994)

Update date:2022-08-03

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Authors:

Palomo, Claudio

Aizpurua, Jesus M.

Ganboa, Inaki

Carreaux, Francois

Cuevas, Carmen

et al. et al.

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Article abstract of DOI:10.1021/jo00090a033

A conceptually new route for the generation of optically active α-aminoacid N-carboxy anhydrides (NCAs) and hence α-amino acid derivatives is described.The strategy developed is simple and consists of the oxidation of α-hydroxy β-lactams to the correspond

Full text of DOI:10.1021/jo00090a033

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