Facile palladium catalysed functionalisation of 1,2-isothiazoline-3-ones and the highly diastereoselective Diels-Alder reactions of 4-vinyl-1,2- isothiazoline-3-one-1-oxides

DOI: 10.1016/S0040-4020(99)00716-4

Source and publish data:

Tetrahedron p. 12313 - 12330 (1999)

Update date:2022-08-04

Topics:

Authors:

Bell, Andrew S.

Fishwick, Colin W. G.

Reed, Jessica E.

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Article abstract of DOI:10.1016/S0040-4020(99)00716-4

A rapid and convenient palladium catalysed method for the regioselective synthesis of a range of usefully functionalised, homochiral 4-substituted 1,2-isothiazoline-3-ones is reported. The totally diastereoselective Diels- Alder reactivity of semi-cyclic sulfoxide containing dienes, 4-vinyl-1,2- isothiazoline-3-one-1-oxides is discussed.

Full text of DOI:10.1016/S0040-4020(99)00716-4

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