Tetrahedron Letters p. 4361 - 4364 (1994)
Update date:2022-08-03
Topics:
Toshima, Hiroaki
Goto, Takashi
Ichihara, Akitami
The C1-C7 segment (10) and the C8-C21 segment (14) of oscillatoxin D have been synthesized efficiently. The acyclic compound obtained by coupling of these two segments, has been converted into the C1-C26 spiroether (18) possessing the same stereogenic centers of oscillatoxin D. The construction of the spiroether has been achieved by intramolecular aldol condensation and Michael-type addition as key steps.
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Doi:10.1021/jo201017w
(2011)Doi:10.1016/0040-4039(94)88236-3
(1994)Doi:10.1016/S0040-4020(01)90395-3
(1994)Doi:10.1039/c4md00028e
(2014)Doi:10.1002/adsc.201300983
(2014)Doi:10.1016/j.tet.2014.03.098
(2014)
