A Study of the Competition between the Di-?-methane and the Azadi-?-methane Processes in 2-Vinyl-β,γ-unsaturated Oxime Derivatives. The Novel Azadi-?-methane Reactivity of β,γ-Unsaturated Oximes

DOI: 10.1021/jo00105a031

Source and publish data:

Journal of Organic Chemistry p. 8115 - 8124 (1994)

Update date:2022-07-30

Topics:

Authors:

Armesto, Diego

Ortiz, Maria J.

Ramos, Ana

Horspool, William M.

Mayoral, Elena P.

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Article abstract of DOI:10.1021/jo00105a031

A study aimed at detecting intramolecular competition between the di-?-methane (DPM) rearrangement and the azadi-?-methane (ADPM) process has been carried out.The results show that direct or acetophenone-sensitized irradiation of 2-(2,2-diphenylvinyl)-2-m

Full text of DOI:10.1021/jo00105a031

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