Tetrahedron Letters p. 625 - 628 (1994)
Update date:2022-07-29
Topics:
Coumbe, Tristan
Lawrence, Nicholas J.
Muhammad, Faiz
Phosphine oxides can be reduced by triethoxysilane, or more conveniently polymethylhydrosiloxane, and catalytic titanium (IV) isopropoxide and provides a system for the efficient one-pot generation of phosphonium salts; the reduction occurs with retention of configuration at phosphorus.
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