Bulletin of the Chemical Society of Japan p. 3067 - 3075 (1994)
Update date:2022-08-04
Topics:
Tsue, Hirohito
Nakashima, Shuichi
Goto, Yasushi
Tatemitsu, Hitoshi
Misumi, Soichi
et al.
A series of covalently linked porphyrin-quinone molecules in which a porphyrin ring is connected at two fixed distances with two different kinds of rigid spacers to benzoquinone were synthesized.The spacer is either spiro<4.4>nonane or trans-decalin.These compounds were designed to have a fixed orientation of different kinds with the same redox pair, the same separation distance, and the same number of intervening bonds.The forward electron-transfer rates were studied by fluorescence-lifetime measurements.Large differences in the rates were found in each pair, and the rates for those compounds having a spiro spacer were larger than those with a trans-decalin spacer.These differences were attributed to a difference in the molecular geometry of the spacer groups in each pair.
View MoreShanghai Kefu Chemical Co.,Ltd.
Contact:+86-21-34616196
Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Contact:15973022782
Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
Laohekou huacheng Trade Co., Ltd.
Contact:+86-710-8360685
Address:No. 85, Beijing Road, Laohekou City, Hubei Province, China
Beijing Stable Chemcial Co.ltd
Contact:86-10-63785052
Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China
Contact:86-574-83851061 86-574-87083208
Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
Doi:10.1002/ejoc.201301802
(2014)Doi:10.1002/ejoc.201301493
(2014)Doi:10.1002/jhet.1647
(2014)Doi:10.1248/cpb.c13-00458
(2013)Doi:10.1016/j.molstruc.2014.01.077
(2014)Doi:10.1002/ejoc.201301887
(2014)