DDQ-Induced, Anomeric Specific, and Diastereoselective Benzylic Glycosidation: A Novel Approach to Heterocyclic Antracycline Antibiotics

DOI: 10.1021/jo00096a032

Source and publish data:

Journal of Organic Chemistry p. 4868 - 4874 (1994)

Update date:2022-09-26

Topics:

Authors:

Xu, Yao-Chang

Lebeau, Elaine

Attardo, Giorgio

Myers, Peter L.

Gillard, John W.

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Article abstract of DOI:10.1021/jo00096a032

A novel and efficient method for the oxidative glycosidation at the heterosubstituted benzylic positions with 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) is described.The reaction is stereospecific with 3-substituted isochromans and isothiochroman, as well

Full text of DOI:10.1021/jo00096a032

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