Tetrahedron p. 10923 - 10932 (1994)
Update date:2022-07-30
Topics:
Quyen, Le thi
Adam, Guenter
Schreiber, Klaus
Starting with the Solanum steroid alkaloid solanidine (3), the nitrogenous brassinosteroid analogues 2α,3α-dihydroxy-5α,22αH,25βH-solanidan-6-one (10) and 2α,3α-dihydroxy-6,7-seco-5α,22αH,25βH-solanidano-6,7-lactone (15) as well as some of their derivatives (e.g., the 10 and 15 N-oxides 12 and 16) and the 5,6-seco-6,5-isolactone 18 have been synthesized.
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(2014)
