Tetrahedron p. 9609 - 9618 (1994)
Update date:2022-09-26
Topics:
Noda
Hosoya
Irie
Yamashita
Katsuki
Asymmetric oxidation of sulfides was examined by using (salen)manganese(III) complexes as catalysts and (8S,8'S,1''S,2''S)-complex (2b) was found to show high asymmetric induction up to 90% ee. Its diastereomeric (8R,8'R,1''S,2''S)-complex (1a) that showed excellent asymmetric induction in the epoxidation of simple olefins, however, was a poor catalyst for the oxidation of sulfides. Kinetic resolution of racemic methyl phenyl sulfoxide with 2b was not effective.
View MoreShandong Xinke Petrochemical Co., Ltd.
Contact:+86-546-7277016
Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
Changsha Yonta Industry Co., Ltd.
Contact:+ 86-731-8535 2228
Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
Shanghai Forever Biotech Co., Ltd.
Contact:+86-21-69734790
Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Tangshan Wisdom Trading Co.,Ltd
Contact:86 315 2222979
Address:No.41 BeiXinXi Road, Yangguang building 1-1102 , Tangshan, Hebei, China
Contact:886 2 2541 0022
Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
Doi:10.1021/ja00762a025
(1972)Doi:10.1021/ja412249k
(2014)Doi:10.1021/jo500174a
(2014)Doi:10.3762/bjoc.12.195
(2016)Doi:10.1002/cjoc.201800461
(2018)Doi:10.1016/0008-6215(92)84119-D
(1992)
