Selective removal of phenolic and alcoholic silyl ethers

DOI: 10.1016/S0040-4039(00)78344-4

Source and publish data:

Tetrahedron Letters p. 7565 - 7568 (1994)

Update date:2022-08-05

Topics:

Authors:

Prakash, Chandra

Saleh, Samir

Blair, Lan A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)78344-4

Potassium carbonate/Kriptofix 222 and pyridinium p-toluenesulfonate or BF₃-etherate have been found to remove the tert-butyldimethylsilyl group from phenolic and alcoholic silyl ethers, respectively. This methodology should find wide applicability in complex organic synthesis.

Full text of DOI:10.1016/S0040-4039(00)78344-4

Products guided by the article

Product name:1-{5-(tert-Butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-dimethyl-silanyloxy)-3-propylamino-propoxy]-phenyl}-3-phenyl-propan-1-one

Cas No:160701-54-2

R&D Labs maybe for 160701-54-2

Xiamen Kaijia Imp & Exp Co., Ltd.

Contact:86-592-5101177

Address:Room406 Luhui Building No. 65 Haitian Road Huli Xiamen,China.
ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei
Sichuan WeiKeqi Biological Technology Co., Ltd.

website:https://www.weikeqi-biotech.com/en

Contact:86-028-81700200

Address:sichuan Chengdu Qingjiang Zhonglu 63号
Huayang chemical Co., LTD

Contact:+86-18653358619

Address:zibo
Sinopharma Yibin Pharmaceutical Co.,Ltd

Contact:86-831-5109854

Address:Luolong Industry Zone

Relevant to this article

A novel one-pot synthesis of ferrocenyl-substituted 1,2,4-oxadiazoles

Doi:10.1016/j.jorganchem.2014.02.018
(2014)
A chelating diphosphine with a single stereogenic phosphorus atom; Rp or Sp-(2-methoxyphenyl)-P-phenyl-P-(2'-diphenylphosphino) ethylphosphine

Doi:10.1016/S0957-4166(00)86279-5
(1994)
Mesogenic materials incorporating 4H-1,2,4-triazol-3-thiol moiety: Synthesis, characterization and liquid crystals study

Doi:10.1016/j.molstruc.2018.06.031
(2018)
Porphyrins with a carbosilane dendrimer periphery as synthetic components for supramolecular self-assembly

Doi:10.1039/c3dt53535e
(2014)
Structurally diverse copper complexes bearing NNO-tridentate schiff-base derivatives as efficient catalysts for copolymerization of carbon dioxide and cyclohexene oxide

Doi:10.1021/ic5002122
(2014)
Synthesis of new [1,2,3]triazoles and 1H-tetrazoles via reactions of 3,(5)-(Di)chloro-2H-1,4-(benz)oxazin-2-ones with diazocompounds or sodium azide

Doi:10.1016/0040-4039(94)88381-5
(1994)

Article Doi