Selective removal of phenolic and alcoholic silyl ethers

DOI: 10.1016/S0040-4039(00)78344-4

Source and publish data:

Tetrahedron Letters p. 7565 - 7568 (1994)

Update date:2022-08-05

Topics:

Authors:

Prakash, Chandra

Saleh, Samir

Blair, Lan A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)78344-4

Potassium carbonate/Kriptofix 222 and pyridinium p-toluenesulfonate or BF₃-etherate have been found to remove the tert-butyldimethylsilyl group from phenolic and alcoholic silyl ethers, respectively. This methodology should find wide applicability in complex organic synthesis.

Full text of DOI:10.1016/S0040-4039(00)78344-4

Products guided by the article

Product name:1-{5-(tert-Butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-dimethyl-silanyloxy)-3-propylamino-propoxy]-phenyl}-3-phenyl-propan-1-one

Cas No:160701-54-2

R&D Labs maybe for 160701-54-2

Shanghai Mio Chemical Co., Ltd

Contact:0086 21- 64401188-622

Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Sichuan All Solid State Materials Co.,Ltd.

website:http://www.kydmaterials.com

Contact:0833-5603116

Address:Airport road Jiajiang county, Sichuan province,China
zhejiang huangyan wanfeng pharm chem co.ltd

Contact:+86-576- 84160728

Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C

Relevant to this article

A novel one-pot synthesis of ferrocenyl-substituted 1,2,4-oxadiazoles

Doi:10.1016/j.jorganchem.2014.02.018
(2014)
A chelating diphosphine with a single stereogenic phosphorus atom; Rp or Sp-(2-methoxyphenyl)-P-phenyl-P-(2'-diphenylphosphino) ethylphosphine

Doi:10.1016/S0957-4166(00)86279-5
(1994)
Mesogenic materials incorporating 4H-1,2,4-triazol-3-thiol moiety: Synthesis, characterization and liquid crystals study

Doi:10.1016/j.molstruc.2018.06.031
(2018)
Porphyrins with a carbosilane dendrimer periphery as synthetic components for supramolecular self-assembly

Doi:10.1039/c3dt53535e
(2014)
Structurally diverse copper complexes bearing NNO-tridentate schiff-base derivatives as efficient catalysts for copolymerization of carbon dioxide and cyclohexene oxide

Doi:10.1021/ic5002122
(2014)
Synthesis of new [1,2,3]triazoles and 1H-tetrazoles via reactions of 3,(5)-(Di)chloro-2H-1,4-(benz)oxazin-2-ones with diazocompounds or sodium azide

Doi:10.1016/0040-4039(94)88381-5
(1994)

Article Doi