Enantiomerically enriched α-vinyl amino acids via lipase-mediated "reverse transesterification"

DOI: 10.1016/S0040-4039(00)78486-3

Source and publish data:

Tetrahedron Letters p. 8743 - 8746 (1994)

Update date:2022-08-05

Topics: Enantiomerically

Authors:

Berkowitz, David B.

Pumphrey, James A.

Shen, Quanrong

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Article abstract of DOI:10.1016/S0040-4039(00)78486-3

Reduction of protected α-vinyl amino acids produces "neopentyl" alcohols that may be enriched in the L-antipode by lipase-mediated acylation with vinyl acetate. Subsequent deacetylation, oxidation and hydrolysis yields enantiomerically enriched L-α-vinyl

Full text of DOI:10.1016/S0040-4039(00)78486-3

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