Tetrahedron Letters p. 8743 - 8746 (1994)
Update date:2022-08-05
Topics: Enantiomerically enriched α-vinyl amino acids lipase-mediated "reverse transesterification"
Berkowitz, David B.
Pumphrey, James A.
Shen, Quanrong
Reduction of protected α-vinyl amino acids produces "neopentyl" alcohols that may be enriched in the L-antipode by lipase-mediated acylation with vinyl acetate. Subsequent deacetylation, oxidation and hydrolysis yields enantiomerically enriched L-α-vinyl
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