Phthalimidesulfenyl Chloride Part 8. Reaction with Activated Arenes: the First Example of ortho-Thioquinones Generation

DOI: 10.1016/S0040-4039(00)78568-6

Source and publish data:

Tetrahedron Letters p. 9451 - 9454 (1994)

Update date:2022-07-31

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Authors:

Capozzi, Giuseppe

Menichetti, Stefano

Nativi, Cristina

Simonti, Maria Cristina

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Article abstract of DOI:10.1016/S0040-4039(00)78568-6

Phthalimidesulfenyl chloride 1 reacts with activated arenes 2a-g, to give monosubstituted derivatives 3a-g.Hydroxysulfenyl compounds 3a-d have been used as suitable source of α-oxothiones (ortho-thioquinones) 4a-d, which act as heterodienes in 4 + 2 cyclo

Full text of DOI:10.1016/S0040-4039(00)78568-6

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