Enantioselective synthesis of 6-cycloheptene-1,3,5-triol derivatives by enzymatic asymmetrization

DOI: 10.1016/S0040-4039(00)78794-6

Source and publish data:

Tetrahedron Letters p. 2597 - 2600 (1991)

Update date:2022-09-26

Topics:

Authors:

Johnson Johnson

Golebiowski

McGill McGill

Steensma

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Article abstract of DOI:10.1016/S0040-4039(00)78794-6

Starting from cycloheptatriene, 3,5-cycloheptadienol (1) has been prepared and elaborated to meso-6-(t-butyldimethylsilyloxy)-2-cycloheptene-1,4-diols (3 and 6). Enzymatic asymmetrization of these diols with Pseudomonas cepacia lipase in isopropenyl aceta

Full text of DOI:10.1016/S0040-4039(00)78794-6

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