Vinyliden-Uebergangsmetallkomplexe XXX. Reaktionen von Acetato- und Trifluoroacetato-Rhodium(I)-Komplexen mit 1-Alkinen: Ein Beispel fuer die Balance zwischen isomeren ?-Alkin-, Alkinyl(hydrido)- und Vinyliden-Metallverbindungen

DOI: 10.1016/0022-328X(94)24750-D

Source and publish data:

Journal of Organometallic Chemistry p. 85 - 100 (1995)

Update date:2022-08-03

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Authors:

Schaefer, Martin

Wolf, Justin

Werner, Helmut

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Article abstract of DOI:10.1016/0022-328X(94)24750-D

The rhodium complex 2-O2CCF3)(PiPr3)2> (2) reacts with 1-alkynes at -20 deg C in pentane to give either four-coordinate alkynerhodium(I) or six-coordinate alkynyl(hydrido)rhodium(III) derivatives.On heating,both types of complexes, trans-<

Full text of DOI:10.1016/0022-328X(94)24750-D

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