Fragmentation of bicyclic γ-silyloxy-β-hydroxy-α- diazolactones as an approach to ynolides

DOI: 10.1021/jo500634d

Source and publish data:

Journal of Organic Chemistry p. 6037 - 6046 (2014)

Update date:2022-07-29

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Authors:

Bayir, Ali

Brewer, Matthias

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Article abstract of DOI:10.1021/jo500634d

Medium-sized ynolides were prepared by the Lewis acid-mediated fragmentation of bicyclic γ-silyloxy-β-hydroxy-α-diazolactones in which the Cβ-Cγ bond is the ring fusion bond. Although these lactone fragmentation substrates reacted somewhat less efficientl

Full text of DOI:10.1021/jo500634d

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